Mohammad Mehdi Khodaei

Professor
Department of Chemistry
Faculty Chemistry
Razi University


Address: Department of Chemistry,Razi University, Tagh Bostan, Kermanshah, Iran

Tel:+98(831)4274559
Fax:+98(831)4274555

Emails: (=AT)

mmkhoda razi.ac.ir


mm_khodaei yahoo.com



Homepage:http://www.razi.ac.ir/khodaei

 

Educational Records

  • B.S.:                 Tabriz University, Iran.  (1969-1973)

  • M.S.:                Shiraz University, Iran  (1973-1975)

  • Ph.D.:               Liverpool University, England  (1983-1986)

  • Sabatical leave: Ottawa University, Canada  (2001-2002)


Course Taught

  • B.S.: Orgaic Chemistry, Organic Synthesis, Physical Organic Chemistry, Applications of Spectroscopy, Photochemistry, Polymer

  • M.S.: Advanced Organic Chemistry, Organic Synthesis, Physical Organic Chemistry, Heterocycle Chemistry

  • Ph.D.: Physical Organic Chemistry, Hard and Soft Chemistry, Reactive Intermediates


Memberships

    M.S. Degree

    Maryam Goodarzi, Afsaneh Keyvan, Sirous Bahrami, Shahpour Zinoldini, Amin Rostami, Esmail Aslani, Kobra Nikoofar, Sara Sirouszadeh, Alireza Rezaei, Ateesa Yazdanipoor, Hamideh Ahankar, Mehdi Kookhazadeh, Kazem Ghozati, Jabar Hoseini, Mohammad Salmanzadeh, A. Soltanzadeh, Mojtaba Beygzadeh, Hassan Moghanian, Pyman Fattahpour, Mahbubeh Jowkar, Jamshide Abbasi, Satar Ghaderi, Javad Salehi, Hamid Ghorbankhani, Mariam Shirindokhet, Kaveh, Kardel, Parvin Ghanbari


Students Graduated

    Member of Iranian Chemical and Chemical Engineering Society


Publications

    1. Donald Bethell, Sara F. C. Dunn, Mehdi M. Khodaei, and Raymond Newall, A kinetic studies of the reaction of diazoalkanes with triphenylphosphine, J. Chem. Soc. Perkin Trans. 2, 1989, 1829.

    2. D. Bethell, M. P. Brown, M. M. Khodaei, M. I. Rios, and K. Woolstencroft, Structures of three diaryl-substituted triphenylphosphazines, Acta Cryst. 1992, B48, 683.

    3. M. M. Khodaei, and A. A. Jamali, Spectrophotometric determination of
    acidity constants of some anthraquinone derivatives in Methanol-Water
    mixture, Iran. J. Chem. Eng. 1999, 18, 55.

    4. M. M. Khodaei, A. A. Jamali, Kinetic study of the reaction of 2,2-Bipyridyl chromium peroxide with alcohols, Iran. J. Sci. 2000, 11, 105.

    5. M. M. Khodaei, P. Salehi, M. Goodarzi, ?-Picolinium chlorochromate(?-PCC); A new and efficient reagent for the oxidation of primary and secondary alcohols, Synth. Commun. 2001, 31, 1253.

    6. P. Salehi, M. M. Khodaei, M. Goodarzi, A new and efficient deoximation method using ?-picolinium chlorochromate( -PCC), Synth. Commun. 2002, 32, 1259.

    7. P. Salehi, M. M. Khodaei, Zolfigol, A. Keyvan, Facile conversion of alcohols into N-substituted amides by magnesium hydrogensulfate under heterogeneous conditions, Synth. Commun. 2001, 31, 1947.

    8. M. M. Khodaei, F. A. Meybodi, N. Rezaei, P. Salehi, Solvent free Beckmann rearrangement of ketoximes by anhydrous ferric chloride, Synth. Commun. 2001, 31, 2047.

    9. Peyman Salehi, Mohammad M. Khodaei, Mohammad A. Zolfigol, Afsaneh, Keyvan, Solvent-free crossed aldol condensation of ketones with aromatic aldehydes mediated by magnesium hydrogensulfate, Monatsh. Fur Chem. 2002, 133, 1291.

    10. P. Salehi, M. M. Khodaei, M. Goodarzi, Oxidative deprotection of cyclic acetals and trimethylsilylethers by -picolinium chlorochromate, Russ. J. Org. Chem. 2002, 392.

    11. Iraj Mohammadpoor-Baltork, Mohammad Mehdi Khodaei, Kobra Nikoufar, Bismuth (III) nitrate pentahydrate: a convenient and selective reagent for conversion of thiocarbonyls to their carbonyl compounds, Tetrahedron Lett. 2003, 44, 591.

    12. Iraj Mohammadpoor-Baltork, Mohammad Mehdi Khodaei, Abdol Reza Hajipour, Esmaeil Aslani, A facile, mild and enviromentally benign procedure for the cleavage of carbon-nitrogen double bonds using KmnO4 in the presence of Montmorillonite K-10 under solvent free conditions, Monatsh. Fur Chem. 2003, 134, 539.

    13. P. Salehi, M. M. Khodaei, M. A. Zolfigol, S. Zeinaldini Catalytic Fridel-Crafts acylation of alkoxybenzenes by ferric hydrogensulfate, Synth. Commun. 2003, 33, 1373.

    14. P. Salehi, M. M. Khodaei, M. A. Zolfigol, Afsaneh Keyvan, Magnesium Hydrogensulfate; A Cheap and Efficient Catalyst for the Conversion of Epoxides into Alkoxy Alcohols, Vicinal-Diols and Thiiranes, Synth. Commun. 2003, 33, 3041.

    15. Peyman Salehi, Mohammad Mehdi Khodaei, Mohammad Ali Zolfigol, Sara Sirouszadeh, Catalytic Friedel-Crafts Acylation of Alkoxy Benzenes Mediated by Aluminium Hydrogensulfate in Solution and Solvent free conditions. Bull. Chem. Soc. Jpn., 2003, 76, 1863.

    16. L. J. McDwell, M. M. Khodaei, D. Bethell, The decomposition of diazo-compounds induced by nucleophiles Part 1. The decomposition of 9-diazoflurene in the presence of hydroxide or alkoxide ion, Org. Biomol. Chem., 2003, 1, 995.

    17. Ahmad R. Khosropour, Mohammad M. Khodaei and Saied J. Hoseini, Facile and Selective Synthesis of 4-Arylidene-2-phenyloxazol-5-ones Catalyzed by CeCl3·7H2O or BiCl3, Molecule 2003, 8, 800.

    18. P. Salehi, M. M. Khodaei, A. Yazdanipoor, Silica gel supported -picolinium chlorochromate; A new and efficient reagent for selective conversion of alcohols and oximes into carbonyl compounds under mild and non-aqueous conditions, Polish. J. Chem. 2003, 77, 1281.

    19. M. M. Khodaei, I. Mohammadpoor-Baltork, K. Nikoufar, Bismouth(III) nitrate pentahydrate: An inexpensive and mild reagent for the efficient and clean oxidation of thiols to disulfides, Bull. Korean Chem. Soc. 2003, 24, 885.

    20. Mohammad M. Khodaei Ahmad R. Khosropour, and Saied J. Hoseini Efficient and chemoselective conversion of aryl aldehydes to their azalactones catalyzed by Bi(III) salts under solvent free conditions, J. Chem. Res. (S) 2003, 638.

    21. P. Salehi, M. M. Khodaei, S. Bahrami, A. Rostamian Silica gel supported ferric perchlorate; A versatile reagent for catalytic formation and cleavage of carbon-oxygen bonds in epoxides, alcohols, and esters, Russ. J. Org. Chem. 2003, 39, 794.

    22. Mohammad Mehdi Khodaei, Peyman Salehi, Mohammad Ali Zolfigol, Sara Sirouszadeh Efficient synthesis of 3,4-dihydropyrimidin-2(1H)-ones by aluminium hydrogensulfate in solution and under solvent free conditions, Polish J. Chem, 2004, 78, 385.

    23. Mohammad M. Khodaei, Ahmad R. Khosropour, and Mojtabah Bigzadeh, An efficient and environmentally friendly method for synthesis of 3,4-dihydropyrimidin-2(1H)-ones catalyzed by Bi(NO3)3. 5H2O, Synth. Commun. 2004, 34, 1551.

    24. Ahmad R. Khosropour, Mohammad M. Khodaei and Kazem Ghozati, Bi(OTf)3 and Bi(TFA)3 as convenient and efficient catalysts for the region-and chemoselective ring opening of epoxides with anilines. Russ. J. Org. Chem. 2004, 40, 1332.

    25. Ahmad R. Khosropour, Mohammad M. Khodaei and Kazem Ghozati, Bi(OTf)3 _ and Bi(TFA)3 _catalyzed ring opening of epoxides with anilines under microwave irradiation. Chem. Lett. 2004, 304.

    26. Ahmad R. Khosropour, Mohammad M. Khodaei and Mehdi Kookhazadeh, A mild, efficient and environmentally friendly method for regio- and chemoselective synthesis of enaminones using Bi (TFA)3as a reusable catalyst in aqueous media. Tetrahedron Lett. 2004, 45, 1725.

    27. Mohammad M. Khodaei, Ahmad R. Khosropour, Kazem Ghozati, A powerful, practical and chemoselective synthesis of 2-anilinoalkanols catalyzed byBi(OTf)3 or Bi(TFA)3 in the presence of TBAB.Tetrahedron Lett. 2004, 45, 3525.

    28. M. M. Khodaei, P. Salehi, A. Yazdanipoor, Maryam Goodarzi, ? -PCC AND ? -PCC-SiO2 as efficient reagents for oxidation of thiols todisulfides. Synth. Commun. 2004, 34, 3661.

    29. Mohammad Mehdi Khodaei, Ahmad Reza Khosropour, Mehdi Kookhazadeh, Enamination of -dicarbonyl compounds catalyzed by CeCl3. 7H2O at ambient conditions: Ionic liquid and solvent-free media. Synlett 2004, 1980.

    30. Ahmad R. Khosropour, Mohammad M. Khodaei, Kazem Ghozati, CeCl3/Et4P Br as a promoter for conversion of disulfides to ?-hydroxy thioethers. Chem. Lett. 2004, 1378.

    31. P. Salehi, M. M. Khodaei, A. Rostami, Alanine/chlorochromic acid/silica gel: an efficient and selective reagent for oxidation of organic functional groups.Phosphorous, sulfur and silicon 2004, 179, 2335.

    32. Mohammad Mehdi Khodaei, Ahmad Reza Khosropour, Kazem Ghozati, Bi(OTf)3 or Bi(TFA)3 catalyzed efficient, regio- and chemoselectively synthesis of ?-hydroxy thioethers from aryl disulfides in the presence of zinc powder. J. Braz. Chem. Soc. 2005, 16, 673.

    33. Ahmad R. Khosropour, Mohammad M. Khodaei, Mehdi Kookhazadeh, A novel enamination of ?-dicarbonyl compounds catalysed by Bi(TFA)3 immobolized on molten TBAB. Can. J. Chem. 2005, 209.

    34. Mohammad Mehdi hodaei, Davod Kordestani, A new, mild and rapid transformation of acylals to bisulfites in one-pot synthesis by bismuth (III) nitrate pentahedrate. Phosphorous, sulfur and silicon 2005, 180, 2403.

    35. Mohammad Mehdi hodaei, Ahmad Reza Khosropour, Pyman Fattahpour, A modification procedure for the Dakin-West reaction: An efficient and convenient method for a one-pot synthesis of -acetamido ketones using silica sulfuric acid as catalyst. Tetrahedron Lett. 2005, 46, 2105.

    36. Mohammad Mehdi Khodaei, Ahmad Reza Khosropour, Mahbubeh Jowkar, Bi(NO3)3. 5H2O-TBAF as an Efficient Reagent for in Situ Oxidation-Dihydropyrimidinone Formation from Benzyl Halides. Synthesis 2005, 1301.

    37. Ahmad R. Khosropour, Mohammad M. Khodaei, Mojtabah Bigzadeh, Mahbobeh Jokar, A one pot synthesis of 3,4-dihydropyrimidin-2-(1H)-ones from primary alcohols promoted by Bi(NO3)3.5H2O in two different media: Organic solvent and ionic liquid. Hetrocycles 2005, 65, 767.

    38. Ahmad R. Khosropour, Mohammad M. Khodaei, Mojtabah Bigzadeh, Mahbobeh Jokar, A facile, simple and convenient method for the synthesis of 14-alkyl or aryl-14-H-dibenzo[a,j]xanthanes catalyzed by p-TsOH in organic solvent and solvent-free media. Synlett, 2005, 955.

    39. Ahmad R. Khosropour, Mohammad M. Khodaei, Hassan Moghanian, A Facile Synthesis of trans-Cinnamic Acids from Aryl Aldehydes and Aryl Aldehyde Bisulfite Adducts with Malonic Acid using Piperazine under Microwave Irradiation. J. Chem. Res. (S) 2005, 364.

    40. Ahmad R. Khosropour, Mohammad M. Khodaei, Kazem Ghozati, BiCl3 catalyzed thiolyzation reaction of 1,2-epoxides with diaryl disulfides in the presence of zinc powder and ionic liquid. Phosphorous, sulfur and silicon 2005, 180, 2525.

    41. Ahmad R. Khosropour, Mohammad M. Khodaei, Kazem Ghozati, Kazem Ghozati, Efficient, eco-Friendly and Regioselective Method for Thiolysis of 1,2-Epoxides with Diaryl Disulfides in the Presence of Zn/Bi(TFA)3-TBPBor Zn/Bi(OTf)3-TBPB. Zeitschrift für Naturforschung B, 2005, 60b, 572.

    42. Mohammad Mehdi Khodaei, Ahmad Reza Khosropour, Kazem Ghozati,Cerium chloride heptahydrate (CeCl3.7H2O) as an efficient enamination catalyst in aqueous media. Russ. J. Org. Chem. 2005, 41, 1445.

    43. Mohammad M. Khodaei, Ahmad R. Khosropour, Jamshid Abbasi, A new synthesis of 1,3-aminols from direct double reduction of ?-enamino ketones formed in situ by reaction of ?-dicarbonyl comounds with anilines. J. Iranian CHEM.Soc. 2005, 2, 289.

    44. Mohammad M. Khodaei, Ahmad R. Khosropour, Satar Ghaderi, Novel deprotection method of aryl aldehyde bisulfite adducts with recoverable [BPy]FeCl4 as a new ionic liquid catalyst. J. Iranian CHEM.Soc. 2006, 3, 69.

    45. Mohammad M. Khodaei, Ahmad R. Khosropour, Hassan Moghanian, A simple and efficient procedure for the synthesis of amidoalkyl naphthols by p-TSA in solution or under solvent-free conditions. Synlett, 2006, 916.

    46. Mohammad M. Khodaei, Ahmad R. Khosropour, Jamshid Abbasi, A novel and highly efficient method for direct conversion of aryl aldehyde bisulfite adducts to their aryl trimethylsilyl ethers in one-pot manner catalyzed by montmorrinolite K-10. Phosphorous, sulfur and silicon 2006, 181, 93.


The Title of Student's Thesises

    1. A kinetic study of the oxidation of alcohols withy [BPCP]

    2. Applications of ?-Pyridinium chlorochromate in organic synthesis

    3. Applications of magnesium hydrogen sulfate in organic synthesis

    4. Applications of gel supported ferric perchlorate in the cleavage of C-O and C=N bonds in organic compounds

    5. Applications of Fe(HSO4)3 in organic synthesis

    6. Oxidation of organic compounds by potassium permanganate in the presence of montmorillonite K-10 in the absence of solvent

    7. Some new applications of Bi(NO3)3.5H2O in organic synthesis

    8. Preparation and some applications of silica gel supported phenyl alaninium chlorochromate

    9. Applications of Al(HSO4)3 in organic synthesis

    10. The preparation and some applications of alaninium chlorochromate in organic synthesis

    11. Some applications of ?-PCC supported on silica gel in organic synthesis

    12. The applications of Iron (III) salts in selective deprotection of bisulfite addition products of aldehydes and ketones

    13.The reactions of primary amines with 1,3-dicarbonyl compounds

    14. Ring opening of epoxides with anilines and disulfides in the presence of CeCl3.7H2O and Bi(III) salts

    15. Synthesis of azlactoness

    16. The synthesis of 3,4-dihydropyrimidin-2(1H)-ones in the presence of Bi(III) salts

    17.The extraction and analysis of essential from cineraria maritime plant; Application of lisenium chlorochromate hydrochloride in oxidation of phenyl hydrazones, thiols and sulfides

    18.The extraction and analysis of essential from cineraria maritime plant; Application of lisenium chlorochromate hydrochloride in oxidation of alcohols,oximes and

    19. One-pot reductive transformations in organic synthesis

    20. New multi-component reactions, oxidation reactions and one-pot oxidation cyclocondensation methods in hetrocyclic synthesis

    21. New procedures for the synthesis of -acetamido ketones and oximes

    22. Applications of ionic liquids in organic synthesis

    23. New condensation reactions in organic synthesis

    24. New methods for the synthesis of pyrano and furanoquinolines and 2,4,5-triarylimidazoles in ionic liquids

    25. Applications of Bi(TFA)3/(BPy)FeCl4 system in organic synthesis

    26. The synthesis of Bis(indolyl)methanes by Bi(NO3)3.5H2O

    27. New methods for the synthesis of -acetamido ketones, enaminones and 4,6-diarylpyrimidin-2(1H)-ones


Research Interest

    1. Mechanism of organic reaction

    2. Synthetic methodology


The Books Translated

    1. How to use chemical abstracts and Index chemicus

    2. Synthesis of organic compounds; Disconnection approach

    3. Spectra of organic compounds


Last Modified: sep, 2006

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