Kiumars Bahrami, Ph.D.

Prof. of Organic Chemistry

Department of Organic Chemistry
Faculty Chemistry
Razi University


Address: Department of Organic Chemistry,Razi University, Tagh Bostan, Kermanshah, Iran

Tel:+98(831)4274562
Fax:+98(831)4274555

Emails: (=AT)

kbahrami2 hotmail.com


Homepage:http://www.razi.ac.ir/kbahrami

Academic Background

    2000- 2005       Ph.D. Candidate
    The University of Isfahan (2000-2004)
    Supervisor(s): Iraj Mohammadpoor-Baltork & Hamid Reza Memarian
    Thesis:
    Investigation of Thermal and Photochemical Reactions of Some Sulfur Compounds Such as Thiocarbonyl compounds and sulfides

    1996-1999       M.Sc.       Razi University
    Supervisor: Moslem Mansour Lakuraj

    Thesis:
    Amberlyst A-26 Supported Peroxodisulfate and Hydroperoxide: Preparation and Applications in Organic Synthesis

    Sabbatical Leave at McGill University, Montreal, Canada (2011-2012)
    My research at the Perepichka's research group was focused on synthesis of new electronic properties in organic matter and their implementation in nanoelectronic devices (field-effect transistors, photovoltaics, etc). My current focus is to extend these research topics towards more technologically useful domains.


Publications

     
    1999
    1.  Lakouraj, M. M.; Bahrami, K. “Selective Conversion of Nitriles to Amid by Amberlyst A-26 Supported Hydroperoxide”Indian J. Chem.1999, 38B, 947.
     
    2000
    1. Lakouraj, M. M.; Bahrami, K.“Amberlyst A-26 Supported Peroxodisulfate Part 1: An Efficient Reagent for Selective Carbon-Nitrogen Double Bond Cleavage of Oximes”J. Chem. Res.(S)2000, 222.
     
    2001
    1. Lakouraj, M. M.; Movassagh, B.; Bahrami, K. “Mild and Convenient Epoxidation of a,b-Unsaturated Ketones by Amberlyst A-26 Supported Hydroperoxide” Synth. Commun.2001, 31, 1237.
     
    2002
    1. Lakouraj, M. M.; Movassagh, B.; Bahrami, K. “Transformation of b-Nitrostyrenes to Carboxylic Acids using Amberlyst A-26 Supported Hydroperoxide Monatsh.Chem. 2002, 133, 1193.
     
    2003
    1. Mohammadpoor-Baltork, I.; Memarian, H. R.; Hajipour, A. R.; Bahrami, K. “Transformatiojn of Thiocarbonyls to Their Corresponding Carbonyl Compounds using n-Butyltriphenylphosposphonium Dicromate (BunPPh3)2
    2. Cr2O7 in Solution and under Microwave Irradiation” 
    3. Bull. Korean Chem. Soc.2003, 24, 1002.
     
    2004
    1. Mohammadpoor-Baltork, I.; Memarian, H. R; Bahrami, K. “Efficient and Convenient Deprotection of Thiocarbonyl to Carbonyl Compounds using 3-Carboxypyridinium and 2,2'-Bipyridinium Chlorochromates in Solution, Dry Media, and under Microwave Irradiation”
    2. Monatsh.Chem.2004, 135, 411.
    1. Mohammadpoor-Baltork, I.; Memarian, H. R; Bahrami, K. “Selective and Convenient Oxidation of Thiols to Disulfides using n-Butyltriphenylphosposphonium Dicromate (BunPPh3)2Cr2O7 in Solution, under Solvent-
    2. Free Conditions and Microwave Irradiation” 
    3. Phosphorus, Sulfur, and Silicon,2004, 179, 2315.
     
    2005
    1. Mohammadpoor-Baltork, I.; Memarian, H. R; Bahrami, K. “3-Carboxypyridinium Chlorochromate-Aluminium Chloride- An Efficient and Inexpensive Reagent System for the Selective Oxidation of Sulfides to Sulfoxides and Sulfones in Solution and under Microwave Irradiation”. Can. J. Chem.2005, 83, 115.
    2. Mohammadpoor-Baltork, I.; Memarian, H. R; Bahrami, K. “Selective Oxidation of Sulfides to Sulfoxides and Sulfones using n-Butyltriphenylphosphonium Dichromate (BunPPh3)2Cr2O7 in the Presence of Aluminium
    3.  
    4. Chloride in Solution and under Microwave Irradiation”        Phosphorus, Sulfur, and Silicon2005, 180, 2751.
     
    2006
    1. Memarian, H. R.; Mohammadpoor-Baltork, I.; Bahrami, K.“Photoinduced Electron Transfer Reactions of Aryl Benzyl Sulfides Promoted by 2,4,6-Triphenylpyrilium Tetrafluoroborate (TPT)” Bull. Korean Chem. Soc.2006, 27, 106.
    2. Bahrami, K. “Selective Oxidation of Sulfides to Sulfoxides and Sulfones using Hydrogen Peroxide (H2O2) in the Presence of Zirconium Tetrachloride” Tetrahedron Lett.2006, 47, 2009.
    3. Bahrami, K.; Khodaei, M. M.; Kavianinia, I. H2O2/HCl as a New and Efficient System for Synthesis of 2-Substituted Benzimidazoles J. Chem. Research (S)2006, 783.
     
    2007
    1. Khodaei, M. M.; Bahrami, K.; Khedri, M. “The EfficientChemoselective MoO3-Catalyzed Oxidation of Sulfides to Sulfoxides and Sulfone with H2O2Can J. Chem.2007, 85, 7.
    2. Bahrami, K.; Khodaei, M. M.; Khedri, M. “A Novel Method for the Deoxygenation of Sulfoxides with the PPh3/Br2/CuBr System” Chem. Lett. 2007, 36, 1324.
    3. Bahrami, K.; Khodaei, M. M.; Kavianinia, I. “A Simple and Efficient One-Pot Synthesis of 2-Substituted Benzimidazoles” Synthesis2007, 547.
    4. Khodaei, M. M.; Bahrami, K.; Kavianinia, I. “p-TSA Catalyzed Synthesis of 2,4,5-Triarylimidazoles from Ammonium Heptamolybdate Tetrahydrate in TBAI” J. Chinese Chem. Soc. 2007, 54, 829.
    5. Khodaei, M. M.; Bahrami, K.; Khedri, M. “ZrCl4 as an Efficient Catalyst for Crossed-aldol Condensation of Cyclic Ketones with Aromatic Aldehydes in Refluxing Ethanol” J. Chinese Chem. Soc. 2007, 54, 807.
     
    2008
    1. Khodaei, M. M.; Bahrami, K.; Shahbazi, F. “An Efficient Method for Aromatic Friedel–Crafts Acylation Reactions” Chem. Lett. 2008, 37, 844.
    2. Bahrami, K.; Khodaei, M. M.; Shahbazi, F. “Highly Selective Catalytic Friedel–Crafts Sulfonylation of Aromatic Compounds using a FeCl3-Based Ionic Liquid” Tetrahedron Lett. 2008, 49, 3931.
    3. Khodaei, M. M.; Bahrami, K.; Karimi, A. “H2O2/Tf2O System: An Efficient Oxidizing Reagent for Selective Oxidation of Sulfanes” Synthesis2008, 1682.
    4. Bahrami, K.; Khodaei, M. M.; Karimi, A. “Mild and Efficient Deoxygenation of Sulfoxides to Sulfides with Triflic Anhydride/Potassium Iodide Reagent System” Synthesis2008, 1682.
    5. Bahrami, K.; Khodaei, M. M.; Nazarian, Z. “TCT as a Rapid and Efficient Catalyst for the Synthesis of 1,5-Benzodiazepines” Bull. Korean Chem. Soc.2008, 29, 1280.
    6. Bahrami, K.; Khodaei, M. M.; Naali, F. “Mild and Highly Efficient Method for the Synthesis of 2-Arylbenzimidazoles and 2-Arylbenzothiazoles” J. Org. Chem. 2008, 73, 6835.
     
    2009
    1. Bahrami, K.; Khodaei, M. M.; Tirandaz, Y. “Desulfurization of Thioamides into Amides with H2O2/ZrCl4 Reagent System” Synthesis2009, 369.
    2. Bahrami, K.; Khodaei, M. M.; Naali, F. “H2O2/Fe(NO3)3-Promoted Synthesis of 2-Arylbenzimidazoles and 2-Arylbenzothiazoles” Synlett2009, 569.
    3. Bahrami, K.; Khodaei, M. M.; Gorgin-Karaji, U. “Transformation of Oximes and Alcohols to Carbonyl Compounds Using Amberlite IRA-400 Supported Chromic Acid in the Presence of Zirconium Tetrachloride” J. Chinese Chem. Soc. 2009, 27, 384.
    4.  Bahrami, K.; Khodaei, M. M.; Farrokhi, A. “Highly Efficient Solvent-Free Synthesis of Dihydropyrimidinones Catalyzed by Zinc Oxide” Synth. Commun. 2009, 39, 1801.
    5. Khodaei, M. M.; Bahrami, K.; Tirandaz, Y. “POCl3 As a Catalytic Activator for H2O2 Activation in Selective Sulfide Oxidation” J. Sulfur Chem.  2009, 30, 581.
    6. Bahrami, K.; Khodaei, M. M.; Farrokhi, A. “H2O2/SOCl2: A Useful Reagent System for the Conversion of Thiocarbonyls to Carbonyl Compounds” Tetrahedron 2009, 65, 7658.
    7. Bahrami, K.; Khodaei, M. M.; Sohelizad, M. “A Novel, Practical Synthesis of Sulfonyl Chlorides from Thiol and Disulfide Derivatives” Synlett 2009, 2773.
    8. Bahrami, K.; Khodaei, M. M.; Sohelizad, M. “Direct Conversion of Thiols to Sulfonyl Chlorides and Sulfonamides” J. Org. Chem. 2009, 74, 9287.
     
    2010
    1. Khodaei, M. M.; Bahrami, K.; Sheikh Arabi, M. “Oxidation of Sulfides to Sulfoxides with H2O2/HNO3 Reagent System” J. Sulfur Chem.  2010, 31, 83.
    2. Khodaei, M. M.; Bahrami, K.; Farrokhi, A. “Amberlite IRA-400 (OH) As a Catalyst in the Preparation of 4H-benzo[b]pyrans in Aqueous Media” Synth. Commun. 2010, 40, 1492.
    3. Bahrami, K.; Khodaei, M. M.; Nejati, A. “Synthesis of 1,2-Disubstituted Benzimidazoles, 2-Substituted Benzimidazoles and 2-Substituted Benzothiazoles in SDS Micelles” Green Chem. 2010, 12, 1237.
    4. Bahrami, K.; Khodaei, M. M.; Sohelizad, M. “Direct Conversion of Thiols and Disulfides into Sulfonamides” Tetrahedron Lett. 2010, 51, 4843.
    5. Bahrami, K.; Khodaei, M. M.; Sheikh Arabi, M. “TAPC-Promoted Oxidation of Sulfides and Deoxygenation of Sulfoxides” J. Org. Chem. 2010, 75, 6208.
    6. Bahrami, K.; Khodaei, M. M.; Tajik, M. “TMSCl-Promoted Selective Desulfurization of Thiocarbonyls to Carbonyls with Hydrogen PeroxideSynthesis2010, 4282.
    7. Bahrami, K.; Khodaei, M. M.; Yousefi, B. H.; Sheikh Arabi, M. “
       
      TMSCl-Promoted Selective Oxidation of Sulfides into Sulfoxides with Hydrogen Peroxide” Tetrahedron Lett. 2010, 51, 6939.
     
    2011
    1. Bahrami, K.; Khodaei, M. M.; Nejati, A. “One-pot Synthesis of 1,2,4,5-Tetrasubstituted and 2,4,5-Trisubstituted Imidazoles by Zinc Oxide as Efficient and Reusable Catalyst” Monatsh Chem. 2011, 142, 159.
    2. Bahrami, K.; Khodaei, M. M.; Fattahpour, P. “SBA-15-Pr–SO3H as Nanoreactor Catalyzed Oxidation of Sulfides into Sulfoxides” Catal. Sci. Technol. 2011, 1, 389.
    3. Bahrami, K.; Khodaei, M. M.; Khodadoustan, N. “TAPC-Catalyzed Synthesis of Thioethers from Thiols and Alcohols” Synlett 2011, 2206.
    4. Bahrami, K.; Khodaei, M. M.; Sohrabnezhad, S. “Cyanuric Chloride as Promoter for the Oxidation of Sulfides and Deoxygenation of Sulfoxides” Tetrahedron Lett. 2011, 52, 6420.
    5. Bahrami, K.; Khodaei, M. M.; Tajik, M.; Soheilizad, M. “Thioacetalization of Aldehydes and Ketones in SDS Micelles” J. Sulfur Chem.  2011, 32, 397.
    6. Bahrami, K. “TAPC-Promoted Synthesis of Sulfonyl Chlorides from Sulfonic Acids” Synlett 2011, 2671.
    7. Bahrami, K.; Khodaei, M. M.; Abbasi, J. “Synthesis of Sulfonyl Chlorides and Sulfonic Acids in SDS Micelles” Synthesis 2011, 44, 316.
     
    2012
    1. Bahrami, K.; Khodaei, M. M.; Khaledian, D. “Synthesis of sulfonyl chlorides and thiosulfonates from H2O2–TiCl4Tetrahedron Lett.  2012, 53, 354.
    2. Bahrami, K.; Khodaei, M. M.; Tajik, M.; Shakibaian, V. “A Novel Approach Towards Dethioacetalization Reactions with H2O2–SOCl2 System” Chinese Chem. Lett. 2012, 23, 81.
    3. Bahrami, K.; Khodaei, M. M.; Abbasi, J. “Synthesis of Sulfonamides and Sulfonic Esters via Reaction of Amines and Phenols with Thiols using H2O2-POCl3 System” Tetrahedron 2012, 68, 5095.
    4. Bahrami, K.; Khodaei, M. M.; Shakibaian, V.; Khaledian, D.; Yousefi,B. H. “TiCl4-Promoted Desulfurization of Thiocarbonyls and Oxidation of Sulfides in the Presence of H2O2J. Sulfur Chem. 2012, 33, 155.
     
     
     
     
    2013
    1. Bahrami, K.; Khodaei, M. M.; Shakibaian, V.; Targhan, H. “Rapid and Convenient Method for the Synthesis of Symmetrical Disulfides” Phosphorus, Sulfur, and Silicon, 2013, 188, 981.
    2. Bahrami, K.; Khodaei, M. M.; Targhan, H.; Sheikh Arabi, M. “Preparation of Esters and Amides from Carboxylic Acids and N-Formylation of Amines Promoted by 1,3,5-Triazo-2,4,6-triphosphorine-2,2,4,4,6,6-hexachloride (TAPC)” Tetrahedron Lett. 2013, 54, 5064.
    3. Bahrami, K.; Khodaei, M. M.; Naali, F.; Yousefi, B. H. “Synthesis of Polysubstituted Pyridines via Reactions of Chalcones and Malononitrile in Alcohols using Amberlite IRA-400 (OH-)” Tetrahedron Lett. 2013, 54, 5293.
     
    2014
    1. Bahrami, K.; Khodaei, M. M.; Babajani, N. Naali, F. “Knoevenagel Condensation in Aqueous Micellar Media using EDAHS as a New Bronsted Acidic Ionic Liquid” J. Iran Chem. Soc.2014, 11, 1675.
    2. Bahrami, K.; Khodaei, M. M.; Roostaei, M. “The Preparation and Characterization of Boehmite Nanoparticles-TAPC: A Tailored and Reusable Nanocatalyst for the Synthesis of 12-Aryl-8,9,10,12-tetrahydrobenzo[a]xanthen-11-ones” New J. Chem. 2014,38,5515.
    3. Bahrami, K.; Khodaei, M. M.; Mohammadi, M., Babajani, N. “Ethane-1,2-diaminium Hydrogen Sulfate: Recyclable Organocatalyst for One Pot Synthesis of β‑Amino Ketones by a Three-component Mannich Reaction” J. Chem. Res. 2014,38,223.
     
    2015
    1. Fattahpour, P.; Sheikh Arabi, M.; Khodaei, M. M.; Bahrami, K. “The New Synthesis and Characterization of SBA-15-Pr–NMe3OH: A Tailored and Reusable Bronsted Base Nanoreactor for the Conversion of Nitriles into Amides using H2O2J. Porous Mater. 2015,22,211.
    2. Rostamnia, S.; Doustkhah, E.; Bahrami, K.;  Amini, S.“An Increase in the Cooperative Catalytic Performance of SBA-15 and TFE in Selective Oxidation of Organic Sulfides” J. Mol. Liq. 2015,207,334.
    3. Bahrami, K.; Khodaei, M. M.; Fattahpour, P. “SBA-15-Pr–SO3H: An Efficient, Environment Friendly and Recyclable Heterogeneous Nanoreactor Catalyst for the One-pot Multicomponent Synthesis of β-Acetamido Ketones” J. Chem. Sci. 2015,127,167.
    4. Bahrami, K.; Khodaei, M. M.; Mohammadi, M.; Roostaei, M. “Sodium Azide as a Catalyst for the Hydration of Nitriles to Primary Amides in Water” J. Chem. Res. 2015,39,267.
     
    2016
    1. Bahrami, K.; Khodaei, M. M.; Mohammadi, M.; Fattahpour, P.; Sharokhi, S. “Preparation of Trimetallic Fe(3)–Ce(8)–Zr(12)–SBA-15 and its Application in Benzylation of aArenes” J Porous Mater. 2016,23,471.
    2. Bahrami, K.; Saleh, S. “[BTBA]Cl-FeCl3 as an Efficient Lewis Acid Ionic Liquid for the Synthesis of Perimidine Derivatives”       Synth. React. Inorg. Met.-Org. Nano-Metal Chem. 2016,46,852.
    3.  
    4. Radfar, S.; Gholivand, M. B.; Bahrami, K. “An Environmentally Friendly Electrochemical Method for Synthesis of Pyrazole Derivatives” J. Electroanal. Chem. 2016,760,1.
    5. Bahrami, K.; Khodaei, M. M.; Naali, F. “TiO2 Nanoparticles Catalysed Synthesis of 2-Arylbenzimidazoles and 2-Arylbenzothiazoles using Hydrogen Peroxide under Ambient Light”. J. Exp. Nanosci. 2016,11,148.
    6. Ghavipour, M.; Soleimani Mehr, A.;Wang, Y.; Mosayebi Behbahani, R.;Hajimirzaee, S.; Bahrami, K. “Investigating the Mixing Sequence and the Si Content in SAPO-34 Synthesis for Selective Conversion of Methanol to Light Olefins using Morpholine/TEAOH Templates” RSC Adv. 2016,6,17583.
    7. B
    8. ahrami, K.; Sheikh Arabi, M. “Copper Immobilized Ferromagnetic Nanoparticle Triazine Dendrimer (FMNP@TD–Cu(II))-Catalyzed Regioselective Synthesis of 1,4-Disubstituted 1,2,3-Triazoles” New J. Chem. 2016, 40,3447.
     
    1. Bahrami, K.; Khodaei, M. M.; Meibodi, F. “Suzuki and Heck cross‐coupling reactions using ferromagnetic nanoparticle‐supported palladium complex as an efficient and recyclable heterogeneous nanocatalyst in sodium dodecylsulfate micelles”. Appl Organometal Chem 2016, 1–9. http://dx.doi.org/10.1002/aoc.3627
     

Chapters published:

    Bahrami, K.“Catalysts for Fine Chemical Synthesis, Volume 5, Regio- and Stereo-Controlled Oxidations and Reductions,” Roberts S. M.; Whittall, J., Ed.; Wiley, pp. 2007, 283-287.


Conferences Presentations

    1. 14th Iranian Chemistry & Chemical Engineering Congress, Tehran, Iran, February, 2004.
    2. 11th Iranian Seminar of Organic Chemistry, Isfahan, Iran, February 2005.
    3. 15th Iranian Seminar of Organic Chemistry, Kermanshah, Iran, Septmber 2008.
    4. 16th Iranian Seminar of Organic Chemistry, Zanjan, Iran, August 2009.
    5. 17th Iranian Seminar of Organic Chemistry, Babolsar, Iran, October 2009.
    6. 12th Asian Chemical Congress (12ACC), Kuala Lumpur Malaysia, August 2007
    7. International Catalysis Conference (ICC), Tehran, Iran, April 2008.
    8. 2ND EUCHEMS Chemistry Congress, Torino, Italy, September 2008.
    9. 10th Tetrahedron Symposium, Paris, France June 2009.
    10. 3ND EUCHEMS Chemistry Congress, Nuremberg, Germany, September 2010.
    11. 12th Tetrahedron Symposium, Sitges, Spain June 2011.


Research Interest:

    •  Applications of Nanostructured Materials for Organic Transformations.
    •  Synthesis, Characterization and Catalytic Application of New Nanoporous Materials
    •  Synthesis and characterization of new conjugated molecular materials for applications as semiconductors in field-effect transistor and photovoltaic (solar cell) devices.


Last Modified: 2 November, 2016

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