E. Rafiee

Professor
Department of Chemistry
Faculty of Science
Razi University
Address: Department of Chemistry,Razi University, Tagh Bostan, Kermanshah, Iran

Tel:+98(83) 34274580
Fax:+98(83) 34228439

Emails: (☻=AT)
e.rafiei☻ razi.ac.ir
E. _Rafiee☻ yahoo.com

Homepage:http://www.razi.ac.ir/Rafiee


I. Personal Informations
Name: E. Rafiee
Date of Birth: Sep. 13, 1971
Place of Birth: Mashhad, Iran
Marital Status: Married, 1 Child


II. Educational Records
• Visiting Student: Liverpool University's Leverhulme Centre for Innovative Catalysis, Liverpool, UK , 2003
• Ph.D. in Inorganic Chemistry: Isfahan University, Iran, 2003
• M.S. in Inorganic Chemistry: Shiraz University, Shiraz, Iran, 1996
• B.S. in Chemistry: Shiraz University, Shiraz, Iran, 1992


III. Academic Experiences
• Assistant Professor: Razi University , Kermanshah, Iran, 2003-2007
• Associate Professor: Razi University , Kermanshah, Iran, 2007-2011
• Professor: Razi University , Kermanshah, Iran, Since 2011


IV. Courses Taught
• Ph.D.: Inorganic Polymer, Bioinorganic Chemistry, Heterogeneous nanocatalysts, Advanced Inorganic Chemistry, Clusters, Advance subject in Inorganic Chemistry, Nanoinorganic Chemistry
• M.S.: Advanced Inorganic Chemistry, Advance subject in Inorganic Chemistry, Bioinorganic Chemistry, Sol-Gel Chemistry.
• B.S.: General Chemistry I and II, Inorganic Chemistry I and II, Organometallic Chemistry


V. Awards
1. Distinguished Researcher of Razi University, 2003
2. Distinguished Researcher of Razi University, 2004
3. Distinguished Researcher of Razi University, 2005
4. Distinguished Researcher of Razi University, 2006
5. Distinguished Researcher of Razi University, 2007
6. Distinguished Researcher of Razi University, 2009
7. Distinguished Researcher of Razi University, 2010
8. Distinguished Researcher of Razi University, 2011
9. Distinguished Researcher of Razi University, 2012
10. Distinguished Researcher of Razi University, 2013
11. Distinguished Researcher of Razi University, 2014


VI. Research Interests
1. Synthesis of Polyoxometalates
2. Heteropoly Anions as Catalyst in Organic Synthesis
3. Heterogeneous and Homogeneous Catalysts
4. Industrial applications of catalysts
5. Schiff Bases
6. Nanocatalysts
7. Hybrid Ionic Liquid
8. Nanometals in Coupling Reactions
9. Biodiesel
10. Sweetening of sulfur


VII. Students Graduated

M.S. Degree:
   1. Hediye Dezfouli
   2. Fariba Tork
   3. Alireza Azad
   4. Solmaz Rashidzadeh
   5. Fatemehsadat Paknejad
   6. Sara Eavani
   7. Hori Mahdavi
   8. Akram Fakhri
   9. Shabnam Shahebrahimi
   10. Zahra Shirazi
   11. Farzaneh Rahimi
   12. Maryam Khodayari
   13. Masoud Kahrizi
   14. Norollah Noori
   15. Maryam Heidari
   16. Maryam Jalilian
   17. Sara Kazemi
   18. Sosan Rezaei


Ph.D. Degree:
    1. Sara Eavani
   2. Nasibeh Rahpeima
   3. Fakhrossadat Mirnezami
   4. Ayoub Shahbazi
   5. Narges Nobakht
   6. Parvaneh Ghaderi
   7. Masoud Kahrizi
   8. Ali Ataei
   9. Elham Noori
   10. Maryam Khodayari


VIII. List of Publications
1. E. Rafiee, S. Tangestaninejad, M. H. Habibi, V. Mirkhani, “A Mild, Efficient and α- Selective Glycosidation by Using Potassium dodecatungstocobaltate trihydrate as Catalyst” Bioorg. Med. Chem. Lett., 2004, 13, 3611.

2. E. Rafiee, S. Tangestaninejad, M. H. Habibi, V. Mirkhani, “K5CoW12O40.3H2O as a New and Efficient Catalyst for Preparation of Mandelates” Bull. of Korean Chem. Soc., 2004, 25(5), 599.

3. E. Rafiee, S. Tangestaninejad, M. H. Habibi, V. Mirkhani, “Potassium dodecatungstocobaltate trihydrate (K5CoW12O40.3H2O) as an Efficient Catalyst for Aminolysis of Epoxides” Synthetic commun., 2004, 34, 3673.

4. E. F. Kozhevnikova, E. Rafiee, I. V. Kozhevnikov, “Fries Rearrangement of Aryl Esters Catalysed by Heteropoly Acid: Catalyst Regeneration and Reuse” Applied Catalysis A: General, 2004, 260, 25-34.

5. E. Rafiee, S. Tangestaninejad, M. H. Habibi, I. Mohammadpoor-Baltork, V. Mirkhani, “Efficient One-Step Conversion of Tetrahydropyranyl Ethers to Acetates and Formates in the Presence of Potassium Dodecatungstocobaltate trihydrate K5CoW12O40.3H2O” Russ. J. of Org. Chem., 2005, 41(3), 403-405.

6. E. Rafiee, S. Tangestaninejad, M. H. Habibi, V. Mirkhani, “Cobalt Polyoxometalate, [CoW12O40]5-, as a New Reusable Catalyst for Addition of Trimethylsilyl Cyanide to Carbonyl Compounds” Bull. Of Korean Chem. Soc., 2005, 26, 9.

7. E. Rafiee, F. Shahbazi, M. Joshaghani, F. Tork. ”The Silica Supported H3PW12O40 (a Heteropoly Acid) as an Efficient and Reusable Catalyst for a One-Pot Synthesis of β-Acetamido Ketones by Dakin-West Reaction” J. Mol. Catal. A, 2005, 242, 129-134.

8. E. Rafiee, F. Tork, M. Joshaghani; “Heteropoly Acids as Solid Green Bronsted Acids for a One-Pot Synthesis of β-acetamido ketones by Dakin-West Reaction” Bioorg. Med. Chem. Lett., 2006, 16, 1221.

9. E. Rafiee, H. Jafari,“A Pactical and Green Approach Towards Synthesis of Dihydro-pyrimidinones: Using Heteropoly Acids as Efficient Catalysts” Bioorg. Med. Chem. Lett., 2006, 16, 2463.

10. E. Rafiee, F. Shahbazi, “One-Pot Synthesis of Dihydropyrimidones Using Silia-Supported Heteropoly Acid as Efficient and Reusable Catalys: Improved Protocol Conditions for the Biginelli Reaction” J. Mol. Catal. A, 2006, 250, 57-61.

11. E. Rafiee, I. Mohammadpoor Baltork, S. Tangestaninejad, A. Azad, S. Moinee; “Tin(II) Polyoxometalate as an Efficient Catalyst for the Selective Oxidation of Sulfides” Z. Naturforsch., 2006, 61b, 269-271.

12. M. Joshaghani, E. Faramarzi, E. Rafiee, M. Daryanavard, J. Xiao, C. Bailie, “Efficient Suzuki cross-coupling reactions using bulky phosphines” J. Mol. Catal., 2006, 259, 35-40.

13. M. B. Gholivand, F. Ahmadi, E. Rafiee, “Highly Copper(II) Ion-Selective Transport Through Liquid Membrane Containing N,N’-bis(salicylidene)-1,2-phenyldiamine” Separation Sci. Technol., 2006, 41, 315-327.

14. R. Tayebee, E. Rafiee, “Acetylation and oxygenation transformations catalyzed by silica –supported dodecatungestophosphoric acid” Bull. Chem. Soc. Ethiopia, 2006, 20, 329-333.

15. E. Rafiee, S. Rashidzadeh, A. Azad, “Silica-supported heteropoly acids: Highly efficient catalysts for synthesis of α-aminonitriles, using trimethylsilyle cyanide or potassium cyanide” J. Mol. Catal. A, 2006, 260, 49-52.

16. M. B. Gholivand, F. Ahmadi, E. Rafiee, “A Novel Al(III)-Selective Electrochemical Sensor Based on N,N’-Bis(salicylidene)-1,2-phenylenediamine Complexes” Electroanalysis, 2006, 18, 1620-1626.

17. M. B. Gholivand, F. Ahmadi, E. Rafiee, “Solid phase interaction and determination of ultra-trace amount of copper using activated carbon modified by salophen” Separation Sci. Technol., 2007, 42, 897-910.

18. E. Rafiee, A. Azad, “K5CoW12O40. 3H2O: Heterogeneouse catalyst for the Strecker-type aminative cyanation of aldehyde and ketones” Synth. Commun., 2007, 37, 7, 1127-1132.

19. E. Rafiee, A. Azad, M. Joshaghani, “K5CoW12O40.3H2O: Highly Efficient Heterogeneous Catalyst for the Synthesis of α-Aminonitriles” Lett. Org. Chem., 2007, 4, 60-63.

20. E. Rafiee, A. Azad, “Cobaltpolyoxometalate-catalyzed cyclization of glucal with aryl amines: Synthesis of 2,4-disubstituted tetrahydroquinolines” Bioorg. Med. Chem. Lett., 2007, 17, 2756.

21. M. Joshaghani, E. Faramarzi, E. Rafiee, M. Daryanavard, J. Xiao, C. Bailie, “Highly efficient Suzuki coupling using moderately bulky tolylphosphine ligands” J. Mol. Catal. A, 2007, 273, 310-315

22. M. Joshaghani, E. Rafiee, M. Daryanavard, J. Xiao, C. Bailie, “A highly efficient catalyst for Suzuki coupling of aryl halides and bromoarylphosphine oxides” Tet. Lett., 2007, 48, 2025-2027.

23. M. Joshaghani, E. Rafiee, F. Shahbazi, H. Jafari, S. Amiri, M. Omiodi, “Quinolinium tribromide: A mild and very efficient oxidant in organic synthesis” Arkivoc, Arcat, 2007, 164-172.

24. M. Joshaghani, M. Bahadori, E. Rafiee, M. Bagherzadeh “Oxidative transformation of organic compounds using bis(bipyridine)silver (II) peroxydisulfate” Arkivoc, 2007, 260-265.

25. E. Rafiee, S. Eavani, E. Babaee, F. Toodehroosta, K. Daneshpazhuh, “Catalytic Performance of Heteropoly Acids on Different Supports in the Synthesis of Dihydropyrimidones” Z. Naturforsch., 2008, 63b, 178-182.

26. E. Rafiee, F. Paknezhad, Sh. Shahebrahimi, M. Joshaghani, S. Eavani, S. Rashidzadeh, “Acid catalysis of different supported heteropoly acids for a one-pot synthesis of β-acetamido ketones” J. Mol. Catal. A, 282, 2008, 92–98.

27. E. Rafiee, M. Joshaghan, F. Tork, A. Fakhri, S. Eavani, “Esterification of mandelic acid catalyzed by heteropoly acid” J. Mol. Catal. A, 283, 2008, 1–4.

28. E. Rafiee, M. Joshaghani, S. Eavani, S. Rashidzadeh, “A revision for the synthesis of b-enaminones in solvent free conditions: efficacy of different supported heteropoly acids as active and reusable catalysts” Green Chem., 2008, 10, 982–989.

29. E. Rafiee, S. Eavani, S. Rashidzadeh, M. Joshaghani, “Tungstophosphoric acid supported on titania as an eco-friendly, green and reusable catalyst for the solvent-free Hantzsch multi-component condensation” HETEROCYCLES, 75, 2008, 2225-2233.

30. M. Joshaghani, M. Daryanavard, E. Rafiee, Sh. Nadri “Synthesis and applications of a new palladacycle as a high active catalyst in the Suzuki couplings” J. Organom. Chem. 2008, 693, 3135-3140.

31. M. B. Gholivand, A. Babakhanian, E. Rafiee, “Determination of Sn(II) and Sn(IV) after mixed micelle-mediated cloud point extraction using _-polyoxometalate as a complexing agent by flame atomic absorption spectrometry “ Talanta, 2008, 76, 503-508.

32. M. Joshaghani, M. Bahadori, E. Rafiee, M. Bagherzadeh “Oxidative Transformation of Organic Copounds Using Bis(1,10-phenanthroline)silver (II) Peroxydisulfate as a Twin Catalyst/Oxidant” J. Iran Chem. Soc., 2008, 5, S108-S112.

33. E. Rafiee, S. Rashidzadeh, M. Joshaghani, H. Chalabeh, K. Afza “γ-Al2O3-supported 12-tungstosilicic acid as an efficient heterogeneous catalyst for the synthesis of α-aminonitriles” Synth. Commun., 2008, 37, 2741-2747.

34. M. Irandoust, M. Joshaghani, E. Rafiee, M. Pourshahbaz, “31P NMR study of the stoichiometry, stability and thermodynamics of complex formation between palladium(II) acetate and bis(diphenylphosphino)ferrocene” Spectrochimica Acta Part A, 74, 2009, 855-859.

35. M. Pourshahbaz, M. Joshaghani, E. Rafiee, J. Shahmoradi, F. Emami, A. Iranpour, “Amine-catalyzed preparation of oxygenated derivatives of symmetric trisulfides” Tetrahedron Lett., 50 ,2009,5987–5989.

36. Sh. Nadri, M. Joshaghani, E. Rafiee, “Selective arylation of 1,1-disubstituted olefins using a biphenyl-based phosphine in Heck coupling reactions” Tetrahedron Lett., 50, 2009 5470–5473.

37. E. Rafiee, S. Eavani, S. Rashidzadeh, M. Joshaghani, “Silica supported 12-tungstophosphoric acid catalysts for synthesis of 1,4-dihydropyridines under solvent-free conditions” Inorg. Chimica Acta 362, 2009, 3555–3562.

38. E. Rafiee, H. Mahdavi, S. Eavani, M. Joshaghani, F. Shiri, “Catalytic activity of tungstophosphoric acid supported on carriers of diverse acidity in the synthesis of enaminones” Appl. Catal. A, 352, 2009, 202–207.

39. Sh. Nadri, M. Joshaghani, E. Rafiee, “Biphenyl-based phosphine: A well-defined, air-stable, and efficient ligand for the Mizoroki–Heck reaction” Appl. Catal. A, 362, 2009 ,163–168.

40. E. Rafiee, Z. Zolfagharifar, M. Joshaghani, S. Eavani, “Facile condensation of indole with benzaldehyde over Keggin-type heteropoly compounds: An initial effort toward catalyst design” Appl. Catal. A, 365, 2009, 287–291

41. Sh. Nadri, M. Joshaghani, E. Rafiee, “Catalytic Performance of a Phosphapalladacycle Bearing a Biphenyl Moiety, Possessing an sp3 C-Pd Bond, toward the Heck Coupling Reaction” Organomet. 2009, 28, 6281–6287.

42. S. S. Madaeni, E. Rafiee, Z. Seyedzadeh, J. Barzin “Effect of dodeca-tungstophosphric acid on morphology and performance of polyvinyl alcohol membrane for gas separation” J. Appl. Polymer Sci., 2009, 114, 484–490.

43. M. Pourshahbaz, M. Irandust, E. Rafiee, M. Joshaghani “Kinetics of complex formation between palladium (II) acetate and bis(diphenylphosphino)ferrocene” Polyhedron, 2009, 28, 609-613.

44. E. Rafiee, S. Eavani, M. Joshaghani, “Reactions of various nucleophiles with D-glucal over Keggin type heteropoly compounds: A simple, rapid, and expedient method for the synthesis of pesudoglycals” J. Carbohydrate Chem., 29, 2010, 20–29.

45. E. Rafiee, S. Eavani, F. Khajoei nejad, M. Joshaghani “Cs2.5H0.5PW12O40 catalyzed diastereoselective synthesis of b-amino ketones via three component Mannich-type reaction in water” Tetrahedron, 66, 2010, 6858-6863.

46. E. Rafiee, S. Rashidzadeh, S. Eavani, M. Joshaghani “KSF-Supported Heteropoly Acids Catalyzed One-pot Synthesis of α-Aminonitriles” Bull. Chem. Soc. Ethiop. , 2010, 24, 209-215.

47. E. Rafiee, H. Mahdavi, and M. Joshaghani “Iodination of Alcohols over Keggin-type Heteropoly Compounds: A Simple, Selective and Expedient Method for the Synthesis of Alkyl Iodides” S. Afr. J. Chem., 2010, 63, 135-140.

48. M. Amirinejad, S. S. Madaeni, M. A. Navarra, E. Rafiee, B. Scrosati “Solvent-free nanocomposite proton-conducting membranes composed of cesium salt of phosphotungstic acid doped PVDF-CTFE/PEO blend” Ionics, 2010, 16, 681-687.

49. E. Rafiee, F. Khajoei nejad, M. Joshaghani “CsxH3-xPW12O40 heteropoly salts catalyzed quinoline synthesis via Friedländer reaction” Chin. Chem. Lett., 2011, 22, 288.

50. E. Rafiee, H. Mahdavi, M. Joshaghani, “Supported Heteropoly Acids Offering Strong Option for Efficient and Cleaner Processing for the Synthesis of Biologically Active Imidazoles under Solvent-Free Condition”, Mol. Diversity, 2011, 15, 125-134.

51. M. Amirinejad, S. S. Madaeni, M. A. Navarra, E. Rafiee, B. Scrosati “Preparation and characterization of phosphotungstic acid-derived salt/Nafion nanocomposite membranes for proton exchange membrane fuel cells” J. Power Sources, 2011, 196, 988-998.

52. .E. Rafiee, Z. Zolfagharifar, M. Joshaghani, S. Eavani “12-Tungstosilicic Acid Supported on Different Carriers: A Pronounced Catalytic Activity in the Synthesis of Bis(indolyl)methanes under Solvent-Free Condition” Synth. Commun. 2011, 41, 459–467.

53. M. Amirinejad, S. S. Madaeni, E. Rafiee, S. Amirinejad “Cesium hydrogen salt of heteropolyacids/Nafion nanocomposite membranes for proton exchange membrane fuel cells” J. Membrane Science 377, 2011, 89– 98.

54. E. Rafiee, Sara Eavani, "H3PW12O40 supported on silica-encapsulated γ-Fe2O3 nanoparticles: a novel magnetically-recoverable catalyst for three-component Mannich-type reactions in water" Green Chem. 2011, 13, 2112-2116.

55. E. Rafiee, M. Khodayari, Sh. Shahebrahimi, M. Joshaghani “12-Tungstophosphoric acid supported on nano silica from rice husk ash as an efficient catalyst for direct benzylation of 1,3-dicarbonyl compounds in solvent-free Condition” J. Mol. Catal. A, 2011, 351, 204-209.

56. R. Tayebee, F. Nezhat, E. Rezaei-Seresht, F. Z. Mohammadi, E. Rafiee, “An efficient and green synthethic protocol for the preparation of bis(indolyl)methanes catalyzed by H6P2W18O62.24H2O, with emphasis on the catalytic proficiency of Wells-Dawson versus Keggin heteropoly acids” J. Mol. Catal. A, 2011, 351, 154-164.

57. Sh. Nadri, E. Azadi, A. Ataei, M. Joshaghani, E. Rafiee “Investigation of the catalytic activity of a Pd/biphenyl-based phosphine system in the Ullmann homocoupling of aryl bromides” J. Organomet. Chem., 2011, 696, 2966-2970.

58. E. Rafiee, M. Khodayari, M. Joshaghani Direct benzylation of 1,3-dicarbonyl compounds catalyzed by Cs2.5H0.5PW12O40 in solvent-free conditions” Can. J. Chem., 2011, 89, 1533-1538.

59. E. Rafiee, F. Khajooei Nejad, M. Joshaghani “Solventless Synthesis of Quinoline Derivatives: Acceleration of Friedländer Reaction by Supported Heteropoly Acids” S. Afr. J. Chem. 2011, 64, 95-100.

60. M. G. Tajgardoon, M. Jafari, E. Rafiee, M. Feyzi, M. Joshaghani “A New Nano Bismuth(III) Salophen Catalyst for Green and Efficient Catalytic Oxidation of Sulfides into the Corresponding Sulfoxides” Inter. Nano Lett., 2012, 2, 29.

61. Z. Solati, M. Hashemi, A. Keshavarzi, E. Rafiee Catalytic epoxidation of Cis-stilbene by tetra-n-butylammonium hydrogen monopersulfate in the presence of manganese(III) tetraarylporphyrins and various anionic co-catalysts” J. Porph. Phethal., 2012, 16, 149-153.

62. E. Rafiee, Sh. Shahebrahimi, M. Feyzi, M. Shaterzadeh, Optimization of synthesis and fully characterization of nanosilica produced from rice husk: A common wast material” Inter. Nano Lett. 2012, 2, 29.

63. E. Rafiee, S. Eavani, B. Malaekeh-Nikouei “12-Tungstophosphoric Acid Immobilized on γ-Fe2O3@SiO2 Core-Shell Nanoparticles: An Effective Solid Acid Catalyst for the Synthesis of Indole Derivatives in Water” Chem. Lett. 2012, 41, 438-440.

64. M. Amirinejad, S. A. Madaeni, K.S. Lee, E. Rafiee, J. Suk Lee “ Sulfonated poly(arylene ether)/ heteropoly acids nanocomposite membranes for proton exchange membrane fuel cells.” Electrochemica Acta, 2012, 62, 227-233.

65. E. Rafiee, M. Khodayari , M. Kahrizi , R. Tayebee “ H5CoW12O40 supported on nano silica from rice husk ash: A green bifunctional catalyst for the reaction of alcohols with cyclic and acyclic 1, 3-dicarbonyl compounds” J. Mol. Catal. A: Chem. 2012, 358, 121-128.

66. K. Hamidian, M. Irandoost, M. Joshaghani, E. Rafiee, “Synthesis, characterization, and tautomeric properties of some azo-azomethine compounds” Z. Naturforsch 2012, 67b, 159-164.

67. E. Rafiee, Sh. Shahebrahimi “Nanosilica with high surface area from rice husk as a support for 12-tungstophosphoric acid: An efficient nano catalyst in some organic reaction” Chin. J. Catal. 2012, 33, 1326-1333.

68. E. Rafiee, S. Eavani “Polyoxometalate-based acid salts with tunable separation properties as recyclable Bronsted acid catalysts for the synthesis of β-keto enol ethers” Catal. Commun. 2012, 25, 64-68.

69. E. Rafiee, F. Rahimi “A green approach to the synthesis of chalcones via Claisen-Schmidt condensation reaction using cesium salts of 12-tungstophosphoric acid as a reusable nanocatalyst” Monatsh. Chem. 2012, DOI 10.1007/s00706-012-0814-5.

70. E. Rafiee, M. Kahrizi, M. Joshaghani “Different products in the reaction of the alcohols with cyclic and acyclic 1,3-dicarbonyl compounds: K5CoW12O40 as an electron transfer nano catalyst. Chin. Chem. Lett. 2012, 23, 12, 1363-1366.

71. A. Ataee, Sh. Nadri, E. Rafiee, S. Jamali, M. Joshaghani “Activation of C-X (=Cl, Br) bond in aryl halides toward the palladium-catalyzed Heck reaction using 2,6-bis(diphenylphosphino)pyridine” J. Mol. Catal. A: Chem. 2012, 366, 30-35.

72. Sh. Shamaei, A. Reza Abbasi, E. Rafiee, A. Azadbakht, N. Noori “Ultrasound-assisted coating of silk yarn with nano-porous Co3(BTC)2•12H2O with iodine adsorption affinity” Colloids and Surf. A: Physicochem. Eng. Aspects, 2013, 431, 66-72.

73. A. Azadbakht, A. R. Abbasi, N. Noori, E. Rafiee, M. Taran, “Synthesis and Characterization of Nanocrystalline CoWO4@Silk Fibers with Antibacterial Activity under Ultrasound Irradiation” Fiber and Polymers, 2013, 14, 4, 687-692.

74. .E. Rafiee, F. Rahimi, “Synthesis of Biologycally Active, Chalcon Analogues via Claisen-Schmidt Condensation in Solvent-Free Conditions: Supported Mixed Addenda Heteropoly Acid as a Heterogeneous Catalyst” J. Chil. Chem. Soc., 2013, 58, 3, 1926.

75. E. Rafiee, S. Eavani, M. Khodayari, “Magnetically recoverable, nanoscale‐supported heteropoly acid catalyst for green synthesis of biologically active compounds in water” Chin. J. Catal., 2013, 1513-1518.

76. M Amirinejad, n. Tavajohi-Hasankiadeh, S. S. Madaeni, M. A. Navarra, E. Rafiee, B. Scrosati “Adaptive neuro-fuzzy inference system and artificial neural network modeling of proton exchange membrane fuel cells based on nanocomposite and recast Nafion membranes” International J. Energy Res., 2013, 37, 347-357.

77. E. Rafiee, A. Fakhri, M. Joshaghani “Coumarins: Facile and Expeditious Synthesis via Keggin-Type Compounds under Solvent Free Condition Running Head: Facile and Expeditious Synthesis of Coumarins” J. Heterocyclic Chemistry 2013, 50, 1121.

78. E. Rafiee, S. Eavani, “Controlled immobilization of Keggin-type heteropoly acids on the surface of silica encapsulated _-Fe2O3 nanoparticles and investigation of catalytic activity in the oxidative esterification of arylaldehydes with methanol” J. Mol. Catal. A: Chem., 2013, 373, 30-37.

79. E. Rafiee, S. Eavani, “Organic–inorganic polyoxometalate based salts as thermoregulated phase-separable catalysts for selective oxidation of thioethers and thiophenes and deep desulfurization of model fuels” J. Mol. Catal. A: Chem. 2013, 380, 18-27.

80. E. Rafiee, M. Kahrizi, “H5CoW12O40@nanosilica: a green, bifunctional, heterogeneous nanocatalyst for one-pot three component Mannich reaction in water” Res. Chem. Intermed. DOI 10.1007/s11164-013-1392-9.

81. E. Rafiee, M. Kahrizi, “Cesium Salts of Phosphotungstic Acid: Comparison of Surface Acidity, Leaching Stability and Catalytic Activity for the Synthesis of â-Ketoenol Ethers” S. Afr. J. Chem., 2013, 66, 145-149.

82. E. Rafiee, A. Ataei, Sh. Nadri, M. Joshaghani, S. Eavani, “Combination of palladium and oleic acid coated-magnetite particles: Characterization and using in Heck coupling reaction with magnetic recyclability” Inorg. Chim. Acta, 2014, 409, 302-309.

83. M. M. Abolghasemi, V. Yousefi, E. Rafiee “Keggin-type heteropoly compounds supported on montmorillonite clays offering strong option for efficient solid-phase micro extraction coating” J. Chromatog. A, 2014, 1327, 14– 18.

84. E. Rafiee, S. Eavani “A new organic–inorganic hybrid ionic liquid polyoxometalate for biodiesel production” J. Mol. Liq., 2014, 199, 96–101.

85. E. Rafiee, S. Eavani, “pH-responsive controlled release of epirubicin from Fe@Si-PW hybrid nanoparticles” Mat. Sci. Eng. C, 2014, 39, 340–343.

86. E. Rafiee, F. Jalilian “An Improved Method for the Synthesis of Triarylmethanes Using Heterogenized 12-Tungestocobaltic Acid” Lett. Org. Chem., 2014, 11, .

87. M. M. Abolghasemi, V. Yousefi, E. Rfiee “Polyoxotungstate nanoclusters supported on silica as an efficient solid-phase microextraction fiber of polycyclic aromatic hydrocarbons” Microchimica Acta, 2014, 1-8.

88. E. Rafiee, F. Mirnezami “Keggin-structured polyoxometalate-based ionic liquid salts: Thermoregulated catalysts for rapid oxidation of sulfur-based compounds using H2O2 and extractive oxidation desulfurization of sulfur-containing model oil” J. Mol. Liq., 2014, 199, 156-161.

89. E. Rafiee, N. Nobakht “Keggin type heteropoly acid, encapsulated in Metal−Organic Framework: A heterogeneous and recyclable nanocatalyst for selective oxidation of sulfides and deep desulfurization of model fuels” J. Mol. Catal. A: Chem, 2014.

90. Sh. Nadri, E. Rafiee, M. Joshaghani “ 2, 6-Bis (diphenylphosphino) pyridine: a simple ligand showing high performance in palladium-catalyzed C N coupling reactions”, Tetrahedron Letters, 2014, 50, 4098

91. A. Ataei, E. Rafiee, M. Joshaghani Palladium Supported on Oleic Acid-coated Magnetic Nanoparticle as an Efficient Catalyst for Heck Coupling Reaction in Aqueous Media, let. Org. Chem., 2014, 11, 707.

92. P. Ghaderi, E. Rafiee, M. Joshaghani, “Synthesis and activity evaluation of a FeCl2-promoted palladium hollow nano-sphere heterogeneous catalyst in Mizoroki–Heck coupling reactions”, Appl. Catal. A., 2014, 487, 139.

93. Sh. Nadri, E. Rafiee, M. Joshaghani “2, 6-Bis (diphenylphosphino) pyridine: a simple ligand showing high performance in palladium-catalyzed C N coupling reactions”, Tetrahedron Letters 55 (30), 4098-4101 Sh. Nadri, E. Rafiee, M. Joshaghani, “1, 1′-Methylene-3, 3′-bis [(N-(tert-butyl) imidazol-2-ylidene] and Its Effect in Palladium-Catalyzed C–C Coupling “, Synlett

95. E. Rafiee, N. Rahpeima “Selective oxidation of sulfurs and oxidation desulfurization of model oil by 12-tungstophosphoric acid on cobalt-ferrite nanoparticles as magnetically recoverable catalyst” Chin. J. Catal. 2015.

96. E. Rafiee, M. Kahrizi “Fe3O4@OA-Pd and Mo10V2@NSiO2 nano particles: An efficient and reusable catalytic system for Heck reaction under ligand free conditions” Res. Chem. Int. 2015.


IX. List of Papers Presented in International Congresses and Seminars
1. E. Rafiee, M. Joshaghani, F. Shahbazi, H. Jafari, M. Amiri, S. Omidi; “Isoquinolinium- and Quinolinium Hydrobromide Perbromide, New Mild and Very Efficient Oxidants in Organic Synthesis” 7th Tetrahedron Symposium, 24-26 May 2006; Poster.

2. M. Joshaghani, E. Faramarzi, E. Rafiee, J. Xiao, C. Baillie; “Highly Efficient Suzuki Cross Coupling Reactions Using Bulky TolylPhosphine Ligands” 7th Tetrahedron Symposium, 24-26 May 2006, Poster.

3. E. Rafiee, S. Rashidzadeh, M. Joshaghani, “Supported Heteropoly Acid: Highly Efficient Catalyst for Synthesis of α-aminonitriles” 12thACC Malaysia, August 2007, Poster.

4. E. Rafiee, F. Paknezhad, S. Shahebrahimi, M. Joshaghani, “One Pot Synthesis of β-Acetamido Ketones by Different Supported Heteropoly Acid as Reusable Catalysts”, 12thACC Malaysia, August 2007, Poster.

5. M. Joshaghani, M. Bahadori, E. Rafiee, 12thACC Malaysia, August 2007.

6. M. Joshaghani, E. Rafiee, F. Shahbazi, H. Jafari, 12thACC Malaysia, August 2007, Poster.

7. M. Amirinejad, S.S. Madaeni, E. Rafiee, A survey of proton conducting composite membranes containing heteropolyacides for proton exchange membrane fuel cells, 5th International Conference on Fuel Cell Science, Engineering and Technology, 18-20 June 2007, New York, USA.

8. B. Seddighi, E. Rafiee, H. Mahdavi, 13th EuChem. Nuremberg, 2010, Germany.

9. E. Rafiee, Sh. Shahebrahimi “Nano silica from rice husk ash as a support material for heteropoly acids: heterogeneous nano catalyst” Colloids and Materials, 8-10 May 2011, Amsterdam, Netherland.

10. E. Rafiee, F. Khajoei Nejad, M. Joshaghani, S. Eavani “Synthesis of nano supported heteropoly compounds as efficient catalysts for Friedlander raction” Colloids and Materials, 8-10 May 2011, Amsterdam, Netherland.

11. M. Joshaghani, M. Jafari, E. Rafiee, M. Faizi “A new nano Bismuth (III) salophen catalyst for green and efficient catalytic oxidation of benzoins to benzyls” Colloids and Materials, 8-10 May 2011, Amsterdam, Netherland.

12. E. Rafiee, M. Khodayari, M. Joshaghani “Synthesis and characterization of H5CoW12O40 supported on nano silica from rice husk ash as a green bifunctional nano catalyst” 4th EuCheMS Chemistry Congress, Czech Republic, August 2012.

13. E. Rafiee, S. Eavani, M. Joshaghani, F. Mahmoodi “Synthesis and characterization of 12-tungstophosphoric acid immobilized on Fe2O3@SiO2 core-shell nanoparticles as solid catalyst for Biginelli reaction” 4th EuCheMS Chemistry Congress, Czech Republic, August 2012.

14. M. Joshaghani, E. Rafiee, E. Azadi “Efficient Ullmann Cross-Couplings using Pd Nanoparticles” 4th EuCheMS Chemistry Congress, Czech Republic, August 2012.

15. E. Rafiee, M. Joshaghani, S. Eavani “ Green approaches to the desulfurization of oil or industrial efficient by polyoxometalates as nano-catalyst” Third International Symposium on Green Chemistry for Environment,Health and Development, Greece, Skiathos, 2012, October.

16. M. Joshaghani, M. Bahadori, E. Rafiee “Green and efficient oxidation of sulfide to sulfoxides in aqueous micelle surface” Third International Symposium on Green Chemistry for Environment,Health and Development, Greece, Skiathos, 2012, October.


X. List of Books
1. M. Joshaghani, E. Rafiee “Some Tests in Inorganic Chemistry” Razi University Press- 2003.

2. M. Joshaghani, E. Rafiee, R. Zibaseresht “Kinetics and Mechanisms of Inorganic Reactions” Razi University Press, 2008.

3. M. Joshaghani, E. Rafiee, Sh. Nadri “Palladium Catalyzed C-C Coupling Reactions” Razi University Press, 2010.


XI. List of Project:

1- مجري طرح: "مديريت نرم افزاري واحدهاي تقطير و تبديل در پالايشگاه كرمانشاه". كارفرما: شركت پالايش نفت كرمانشاه. 1383 (خاتمه يافته).

2- همكار طرح پژوهشي: "بررسي امكان استحصال كاتاليست واحد مراكس". كارفرما: شركت پالايش نفت كرمانشاه. 1382-1381 (خاتمه يافته).

3- مجري طرح " سنتز و شناسايي چند ليگاند باز شيف ". كارفرما: دانشگاه رازي. 1385- 1384.

4- مجري طرح " سنتز و شناسايي هتروپلي اسيدهاي نشانده شده روي بستر نانوذرات اكسيد آهن با پوشش سيليكا و بررسي كارايي آنها به عنوان نانو كاتاليزورهاي مغناطيسي جديد قابل بازيافت در سنتز مواد آلي" 1391 كارفرما: صندوق حمايت از پژوهشگران و فناوران كشور.

5- بهينه سازي شرايط توليد بيوديزل با استفاده از هتروپلي آنيونهاي نشانده شده روي پايه مغناطيسي و مايع يوني-پلي اكسومتالات هيبريد ها به عنوان يك كاتاليزور جديد هموژن/هتروژن قابل بازيافت با تنظيم دما 1392 كارفرما:صندوق حمايت از پژوهشگران و فناوران كشور.


Last Modified: 18 May, 2015

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